Nicolás Domínguez put Forest back into the tie which went to extra-time then penalties. The English team took the shootout 0-3.
Nottingham Forest won the only shoot-out of the UEFA Europa League round of 16 deciders, Bologna beat Roma after extra time, while Aston Villa and Real Betis came good at home.
Liverpool continue their top-five chase when they visit relegation-threatened Nottingham Forest on Sunday at the City Ground.
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